Tandem mass spectrometry of silver-adducted ferrocenyl catalyst complexes in continuous-flow reaction detection systems

C.T. Martha, W.J. van Zeist, F.M. Bickelhaupt, H. Irth, W.M.A. Niessen

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

Ferrocene is a popular template in material science due to its exceptional characteristics that offer the ability to optimize the selectivity and activity of catalysts by the addition of carefully selected substituents. In combinatorial catalyst development, the high susceptibility to electrophilic substitution reactions offers the opportunity for the rapid introduction of molecular diversity. Mass spectrometry (MS)-based continuous-flow systems can be applied to rapidly evaluate catalyst performance as well as to (provisionally) identify the introduced catalyst complexes. Herein, we describe the fragmentation characteristics of the [ferrocenyl bidentate + Ag]
Original languageEnglish
Pages (from-to)1332-1343
JournalJournal of Mass Spectrometry
Volume45
Issue number11
DOIs
Publication statusPublished - 2010

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