Linkage isomerism of nitriles in rhodium half-sandwich metallacycles

L. Orian, W.J. van Zeist, F.M. Bickelhaupt

Research output: Contribution to JournalArticleAcademicpeer-review

Abstract

A systematic analysis of the linkage isomerism of nitriles in half-sandwich five-membered rhodacycles is presented for 15 nitriles of the general formula RCN. The hitherto elusive transition states connecting the two isomers have been located using advanced DFT methods. © 2008 American Chemical Society.
Original languageEnglish
Pages (from-to)4028-4030
JournalOrganometallics
Volume27
Issue number16
DOIs
Publication statusPublished - 2008

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