The hyperfine structure of I-129(2) and I-127 I-129 in the B-3 Pi(+)(0u)-X-1 Sigma(+)(g) band system

E.J. Salumbides, K.S.E. Eikema, W.M.G. Ubachs, U. Hollenstein, H. Knoeckel, E. Tiemann

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Abstract

In a double saturation spectroscopy experiment, using the radiation from one single frequency cw laser, the spectra of 129 I 2 and 127 I 129 I from one saturation setup were recorded simultaneously and with respect to the spectrum of 127 I 2 from another setup while tuning the laser. The hyperfine patterns of 129 I 2 and 127 I 129 I were analysed to determine the nuclear electric quadrupole interaction and the nuclear spin-rotation interaction parameters. Models are presented describing the observations and giving reliable predictions for the hyperfine parameters of all isotopomers.
Original languageEnglish
Pages (from-to)2641-2652
JournalMolecular Physics
Volume104
DOIs
Publication statusPublished - 2006

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