Abstract
The formation of reactive carbanions in Grignard reagents was discussed. Inter- and/or intramolecular migrations of organotin and organosilicon groups were also studied. Results showed that the high percentage of rearrangement reactions proves that the anionic species are not located on a minor pathway.
Original language | English |
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Pages (from-to) | 2119-2135 |
Number of pages | 16 |
Journal | Organometallics |
Volume | 21 |
DOIs | |
Publication status | Published - 2002 |
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CCDC 114259: Experimental Crystal Structure Determination
Van Klink, G. P. M. (Contributor), De Boer, H. J. R. (Contributor), Schat, G. (Contributor), Akkerman, O. S. (Contributor), Bickelhaupt, F. (Contributor) & Spek, A. L. (Contributor), Unknown Publisher, 1 Jan 2002
DOI: 10.5517/cc3twsk, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc3twsk&sid=DataCite
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